среда, 5 сентября 2012 г.

Surface Structure of hcp Metals

This important class of metallic structures includes metals such as Co, Zn, Ti & Ru.

The Miller Index notation used to describe the orientation of surface planes for all crystallographic systems is slightly more complex in this case since the crystal structure does not lend itself to description using a standard cartesian set of axes- instead the notation is based upon three axes at 120 degrees in the close-packed plane, and one axis (the c-axis) perpendicular to these planes. This leads to a four-digit index structure ; however, since the third of these is redundant it is sometimes left out !

I. The hcp (0001) surface
This is the most straightforward of the hcp surfaces since it corresponds to a surface plane which intersects only the c-axis, being coplanar with the other 3 axes i.e. it corresponds to the close packed planes of hexagonally arranged atoms that form the basis of the structure. It is also sometimes referred to as the (001) surface.

This conventional plan view of the (0001) surface shows the hexagonal packing of the surface layer atoms.

Which fcc surface does it resemble ?
We can summarise the characteristics of this surface by noting that :
  1. All the surface atoms are equivalent and have CN=9
  2. The surface is almost smooth at the atomic scale
  3. The surface offers the following adsorption sites :
  • On-top sites
  • Bridging sites, between two atoms
  • Hollow sites, between three atoms

Surface Structure of fcc Metals

Many of the technologically most important metals possess the fcc structure : for example the catalytically important precious metals ( Pt, Rh, Pd ) all exhibit an fcc structure.

The low index faces of this system are the most commonly studied of surfaces : as we shall see they exhibit a range of
  1. Surface symmetry
  2. Surface atom coordination
  3. Surface reactivity

I. The fcc (100) surface
The (100) surface is that obtained by cutting the fcc metal parallel to the front surface of the fcc cubic unit cell - this exposes a surface (the atoms in blue) with an atomic arrangement of 4-fold symmetry
The diagram below shows the conventional birds-eye view of the (100) surface - this is obtained by rotating the preceding diagram through 45° to give a view which emphasises the 4-fold (rotational) symmetry of the surface layer atoms.
The tops of the second layer atoms are just visible through the holes in the first layer, but would not be accessible to molecules arriving from the gas phase.

What is the coordination number of the surface layer atoms on the fcc(100) surface ?
There are several other points worthy of note :
  1. All the surface atoms are equivalent
  2. The surface is relatively smooth at the atomic scale
  3. The surface offers various adsorption sites for molecules which have different local symmetries and lead to different coordination geometries - specifically there are :
  • On-top sites (above a single metal atom)
  • Bridging sites, between two atoms
  • Hollow sites, between four atoms
Depending upon the site occupied, an adsorbate species (with a single point of attachments to the surface) is therefore likely to be bonded to either one, two or four metal atoms.

II. The fcc(110) surface
The (110) surface is obtained by cutting the fcc unit cell in a manner that intersects the x and y axes but not the z-axis - this exposes a surface with an atomic arrangement of 2-fold symmetry.

The diagram below shows the conventional birds-eye view of the (110) surface - emphasising the rectangular symmetry of the surface layer atoms. The diagram has been rotated such that the rows of atoms in the first atomic layer now run vertically, rather than horizontally as in the previous diagram.
It is clear from this view that the atoms of the topmost layer are much less closely packed than on the (100) surface - in one direction (along the rows) the atoms are in contact i.e. the distance between atoms is equal to twice the metallic(atomic) radius, but in the orthogonal direction there is a substantial gap between the rows.

This means that the atoms in the underlying second layer are also, to some extent, exposed at the surface
The preceding diagram illustrates some of those second layer atoms, exposed at the bottom of the troughs.

In this case, the determination of atomic coordination numbers requires a little more careful thought : one way to double-check your answer is to remember that the CN of atoms in the bulk of the fcc structure is 12, and then to subtract those which have been removed from above in forming the surface plane.

What is the coordination number of the topmost layer atoms on the fcc(110) surface ?
If we compare this coordination number with that obtained for the (100) surface, it is worth noting that the surface atoms on a more open ("rougher") surface have a lower CN - this has important implications when it comes to the chemical reactivity of surfaces.

Do the atoms in the second layer have the bulk coordination ?

No - the fact that they are clearly exposed (visible) at the surface implies that they have a lower CN than they would in the bulk.


What is the coordination number of these second layer atoms on the fcc(110) surface ?
In summary, we can note that
  1. All first layer surface atoms are equivalent, but second layer atoms are also exposed
  2. The surface is atomically rough, and highly anisotropic
  3. The surface offers a wide variety of possible adsorption sites, including :
  • On-top sites
  • Short bridging sites between two atoms in a single row
  • Long bridging sites between two atoms in adjacent rows
  • Higher coordination sites ( in the troughs )
III. The fcc (111) surface
The (111) surface is obtained by cutting the fcc metal in such a way that the surface plane intersects the x-, y- and z- axes at the same value - this exposes a surface with an atomic arrangement of 3-fold ( apparently 6-fold, hexagonal ) symmetry. This layer of surface atoms actually corresponds to one of the close-packed layers on which the fcc structure is based.


The diagram below shows the conventional birds-eye view of the (111) surface - emphasising the hexagonal packing of the surface layer atoms. Since this is the most efficient way of packing atoms within a single layer, they are said to be "close-packed".


What is the coordination number of the surface layer atoms on the fcc(111) surface?
The following features are worth noting ;
  1. All surface atoms are equivalent and have a relatively high CN
  2. The surface is almost smooth at the atomic scale
  3. The surface offers the following adsorption sites :
  • On-top sites
  • Bridging sites, between two atoms
  • Hollow sites, between three atoms
IV. How do these surfaces intersect in irregular-shaped samples.
Flat surfaces of single crystal samples correspond to a single Miller Index plane and, as we have seen, each individual surface has a well-defined atomic structure. It is these flat surfaces that are used in most surface science investigations, but it is worth a brief aside to consider what type of surfaces exist for an irregular shaped sample (but one that is still based on a single crystal). Such samples can exhibit facets corresponding to a range of different Miller Index planes. This is best illustrated by looking at the (clickable) diagrams below.

SUMMARY
Depending upon how an fcc single crystal is cleaved or cut, flat surfaces of macroscopic dimensions which exhibit a wide range of structural characteristics may be produced.

The single crystal surfaces discussed here ( (100), (110) & (111) ) represent only the most frequently studied surface planes of the fcc system - however, they are also the most commonly occurring surfaces on such metals and the knowledge gained from studies on this limited selection of surfaces goes a long way in propagating the development of our understanding of the surface chemistry of these metals.

Surface Structure of Metals

In most technological applications, metals are used either in a finely divided form (e.g. supported metal catalysts) or in a massive, polycrystalline form (e.g. electrodes, mechanical fabrications).

At the microscopic level, most materials, with the notable exception of a few truly amorphous specimens, can be considered as a collection or aggregate of single crystal crystallites. The surface chemistry of the material as a whole is therefore crucially dependent upon the nature and type of surfaces exposed on these crystallites. In principle, therefore, we can understand the surface properties of any material if we
know the amount of each type of surface exposed , and
have detailed knowledge of the properties of each and every type of surface plane.

(This approach assumes that we can neglect the possible influence of crystal defects and solid state interfaces on the surface chemistry)

It is therefore vitally important that we can independently study different, well-defined surfaces. The most commonly employed technique, is to prepare macroscopic (i.e. size ~ cm) single crystals of metals and then to deliberately cut-them in a way which exposes a large area of the specific surface of interest.

Most metals only exist in one bulk structural form - the most common metallic crystal structures being :


For each of these crystal systems, there are in principle an infinite number of possible surfaces which can be exposed. In practice, however, only a limited number of planes (predominantly the so-called "low-index" surfaces) are found to exist in any significant amount and we can concentrate our attention on these surfaces. Furthermore, it is possible to predict the ideal atomic arrangement at a given surface of a particular metal by considering how the bulk structure is intersected by the surface. Firstly, however, we need to look in detail at the bulk crystal structures.

I. The hcp and fcc structures
The hcp and fcc structures are closely related : they are both based upon stacking layers of atoms, where the atoms are arranged in a close-packed hexagonal manner within the individual layer.

The atoms of the next layer of the structure will preferentially sit in some of the hollows in the first layer - this gives the closest approach of atoms in the two layers and thereby maximizes the cohesive interaction.
When it comes to deciding where the next layer of atoms should be positioned there are two choices - these differ only in the relative positions of atoms in the 1st and 3rd layers.
In the structure on the left the atoms of the 3rd layer sit directly above those in the 1st layer - this gives rise to the characteristic ..ABABA.. packing sequence of the hcp structure.
In the structure on the right the atoms of the 3rd layer are laterally offset from those in both the 1st and 2nd layers, and it is not until the 4th layer that the sequence begins to repeat. This is the ..ABCABC.. packing sequence of the fcc structure. Because of their common origin, both of these structures share common features :
  1. The atoms are close packed
  2. Each atom has 12 nearest neighbours ( i.e. a coordination number,CN = 12 )
(a) fcc structure
Although it is not immediately obvious, the ..ABCABC.. packing sequence of the fcc structure gives rise to a three-dimensional structure with cubic symmetry ( hence the name ! ).
It is the cubic unit cell that is commonly used to illustrate this structure - but the fact that the origin of the structure lies in the packing of layers of hexagonal symmetry should not be forgotten.
(b) hcp structure
The ..ABABA.. packing sequence of the hcp structure gives rise to a three-dimensional unit cell structure whose symmetry is more immediately related to that of the hexagonally-close packed layers from which it is built, as illustrated in the diagram below.


II. The bcc structure
The bcc structure has very little in common with the fcc structure - except the cubic nature of the unit cell. Most importantly, it differs from the hcp and fcc structures in that it is not a close-packed structure.




Physics

Physics (from Ancient Greek: φύσις physis "nature") is a natural science that involves the study of matter and its motion through space and time, along with related concepts such as energy and force. More broadly, it is the general analysis of nature, conducted in order to understand how the universe behaves.

Physics is one of the oldest academic disciplines, perhaps the oldest through its inclusion of astronomy. Over the last two millennia, physics was a part of natural philosophy along with chemistry, certain branches of mathematics, and biology, but during the Scientific Revolution in the 17th century, the natural sciences emerged as unique research programs in their own right. Physics intersects with many interdisciplinary areas of research, such as biophysics and quantum chemistry, and the boundaries of physics are not rigidly defined. New ideas in physics often explain the fundamental mechanisms of other sciences, while opening new avenues of research in areas such as mathematics and philosophy.

Physics also makes significant contributions through advances in new technologies that arise from theoretical breakthroughs. For example, advances in the understanding of electromagnetism or nuclear physics led directly to the development of new products which have dramatically transformed modern-day society, such as television, computers, domestic appliances, and nuclear weapons; advances in thermodynamics led to the development of industrialization; and advances in mechanics inspired the development of calculus.



History
As noted below, the means used to understand the behavior of natural phenomena and their effects evolved from philosophy, progressively replaced by natural philosophy then natural science, to eventually arrive at the modern conception of physics.

Natural philosophy has its origins in Greece during the Archaic period, (650 BCE – 480 BCE), when Pre-Socratic philosophers like Thales refused supernatural, religious or mythological explanations for natural phenomena and proclaimed that every event had a natural cause. They proposed ideas verified by reason and observation and many of their hypotheses proved successful in experiment, for example atomism.

Classical physics became a separate science when early modern Europeans used these experimental and quantitative methods to discover what are now considered to be the laws of physics. Kepler, Galileo and more specifically Newton discovered and unified the different laws of motion. Experimental physics had its debuts with experimentation concerning statics by medieval Muslim physicists like al-Biruni and Alhazen. During the industrial revolution, as energy needs increased, so did research, which led to the discovery of new laws in thermodynamics, chemistry and electromagnetics.

Modern physics started with the works of Max Planck in quantum theory and Einstein in relativity, and continued in quantum mechanics pioneered by Heisenberg, Schrödinger and Paul Dirac.


Philosophy
In many ways, physics stems from ancient Greek philosophy. From Thales' first attempt to characterize matter, to Democritus' deduction that matter ought to reduce to an invariant state, the Ptolemaic astronomy of a crystalline firmament, and Aristotle's book Physics (an early book on physics, which attempted to analyze and define motion from a philosophical point of view), various Greek philosophers advanced their own theories of nature. Physics was known as natural philosophy until the late 18th century.

By the 19th century physics was realized as a discipline distinct from philosophy and the other sciences. Physics, as with the rest of science, relies on philosophy of science to give an adequate description of the scientific method. The scientific method employs a priori reasoning as well as a posteriori reasoning and the use of Bayesian inference to measure the validity of a given theory.

The development of physics has answered many questions of early philosophers, but has also raised new questions. Study of the philosophical issues surrounding physics, the philosophy of physics, involves issues such as the nature of space and time, determinism, and metaphysical outlooks such as empiricism, naturalism and realism.

Many physicists have written about the philosophical implications of their work, for instance Laplace, who championed causal determinism, and Erwin Schrödinger, who wrote on quantum mechanics. The mathematical physicist Roger Penrose has been called a Platonist by Stephen Hawking, a view Penrose discusses in his book, The Road to Reality. Hawking refers to himself as an "unashamed reductionist" and takes issue with Penrose's views.




Core theories
Though physics deals with a wide variety of systems, certain theories are used by all physicists. Each of these theories were experimentally tested numerous times and found correct as an approximation of nature (within a certain domain of validity). For instance, the theory of classical mechanics accurately describes the motion of objects, provided they are much larger than atoms and moving at much less than the speed of light. These theories continue to be areas of active research, and a remarkable aspect of classical mechanics known as chaos was discovered in the 20th century, three centuries after the original formulation of classical mechanics by Isaac Newton (1642–1727).

These central theories are important tools for research into more specialized topics, and any physicist, regardless of his or her specialization, is expected to be literate in them. These include classical mechanics, quantum mechanics, thermodynamics and statistical mechanics, electromagnetism, and special relativity.


Classical physics
Classical physics includes the traditional branches and topics that were recognized and well-developed before the beginning of the 20th century—classical mechanics, acoustics, optics, thermodynamics, and electromagnetism. Classical mechanics) is concerned with bodies acted on by forces and bodies in motion and may be divided into statics (study of the forces on a body or bodies at rest), kinematics (study of motion without regard to its causes), and dynamics (study of motion and the forces that affect it); mechanics may also be divided into solid mechanics and fluid mechanics (known together as continuum mechanics), the latter including such branches as hydrostatics, hydrodynamics, aerodynamics, and pneumatics. Acoustics, the study of sound, is often considered a branch of mechanics because sound is due to the motions of the particles of air or other medium through which sound waves can travel and thus can be explained in terms of the laws of mechanics. Among the important modern branches of acoustics is ultrasonics, the study of sound waves of very high frequency beyond the range of human hearing. Optics, the study of light, is concerned not only with visible light but also with infrared and ultraviolet radiation, which exhibit all of the phenomena of visible light except visibility, e.g., reflection, refraction, interference, diffraction, dispersion, and polarization of light. Heat is a form of energy, the internal energy possessed by the particles of which a substance is composed; thermodynamics deals with the relationships between heat and other forms of energy. Electricity and magnetism have been studied as a single branch of physics since the intimate connection between them was discovered in the early 19th century; an electric current gives rise to a magnetic field and a changing magnetic field induces an electric current. Electrostatics deals with electric charges at rest, electrodynamics with moving charges, and magnetostatics with magnetic poles at rest.



Modern physics
Classical physics is generally concerned with matter and energy on the normal scale of observation, while much of modern physics is concerned with the behavior of matter and energy under extreme conditions or on the very large or very small scale. For example, atomic and nuclear physics studies matter on the smallest scale at which chemical elements can be identified. The physics of elementary particles is on an even smaller scale, as it is concerned with the most basic units of matter; this branch of physics is also known as high-energy physics because of the extremely high energies necessary to produce many types of particles in large particle accelerators. On this scale, ordinary, commonsense notions of space, time, matter, and energy are no longer valid.

The two chief theories of modern physics present a different picture of the concepts of space, time, and matter from that presented by classical physics. Quantum theory is concerned with the discrete, rather than continuous, nature of many phenomena at the atomic and subatomic level, and with the complementary aspects of particles and waves in the description of such phenomena. The theory of relativity is concerned with the description of phenomena that take place in a frame of reference that is in motion with respect to an observer; the special theory of relativity is concerned with relative uniform motion in a straight line and the general theory of relativity with accelerated motion and its connection with gravitation. Both quantum theory and the theory of relativity find applications in all areas of modern physics.




Relation to other fields
Prerequisites

Mathematics is the language used for compact description of the order in nature, especially the laws of physics. This was noted and advocated by Pythagoras, Plato, Galileo, and Newton.

Physics theories use mathematics to obtain order and provide precise formulas, precise or estimated solutions, quantitative results and predictions. Experiment results in physics are numerical measurements. Technologies based on mathematics, like computation have made computational physics an active area of research.

The distinction between mathematics and physics is clear-cut, but not always obvious, especially in mathematical physics.

Ontology is a prerequisite for physics, but not for mathematics. It means physics is ultimately concerned with descriptions of the real world, while mathematics is concerned with abstract patterns, even beyond the real world. Thus physics statements are synthetic, while math statements are analytic. Mathematics contains hypotheses, while physics contains theories. Mathematics statements have to be only logically true, while predictions of physics statements must match observed and experimental data.

The distinction is clear-cut, but not always obvious. For example, mathematical physics is the application of mathematics in physics. Its methods are mathematical, but its subject is physical. The problems in this field start with a "math model of a physical situation" and a "math description of a physical law". Every math statement used for solution has a hard-to-find physical meaning. The final mathematical solution has an easier-to-find meaning, because it is what the solver is looking for.

Physics is a branch of fundamental science, not practical science. Physics is also called "the fundamental science" because the subject of study of all branches of natural science like chemistry, astronomy, geology and biology are constrained by laws of physics. For example, chemistry studies properties, structures, and reactions of matter (chemistry's focus on the atomic scale distinguishes it from physics). Structures are formed because particles exert electrical forces on each other, properties include physical characteristics of given substances, and reactions are bound by laws of physics, like conservation of energy, mass and charge.

Physics is applied in industries like engineering and medicine.



Application and influence
Applied physics is a general term for physics research which is intended for a particular use. An applied physics curriculum usually contains a few classes in an applied discipline, like geology or electrical engineering. It usually differs from engineering in that an applied physicist may not be designing something in particular, but rather is using physics or conducting physics research with the aim of developing new technologies or solving a problem.
The approach is similar to that of applied mathematics. Applied physicists can also be interested in the use of physics for scientific research. For instance, people working on accelerator physics might seek to build better particle detectors for research in theoretical physics.
Physics is used heavily in engineering. For example, statics, a subfield of mechanics, is used in the building of bridges and other structures. The understanding and use of acoustics results in better concert halls; similarly, the use of optics creates better optical devices. An understanding of physics makes for more realistic flight simulators, video games, and movies, and is often critical in forensic investigations.
With the standard consensus that the laws of physics are universal and do not change with time, physics can be used to study things that would ordinarily be mired in uncertainty. For example, in the study of the origin of the earth, one can reasonably model earth's mass, temperature, and rate of rotation, over time. It also allows for simulations in engineering which drastically speed up the development of a new technology.
But there is also considerable interdisciplinarity in the physicist's methods and so many other important fields are influenced by physics, e.g. the fields of econophysics and sociophysics.


Research
Scientific method

Physicists use a scientific method to test the validity of a physical theory, using a methodical approach to compare the implications of the theory in question with the associated conclusions drawn from experiments and observations conducted to test it. Experiments and observations are collected and compared with the predictions and hypotheses made by a theory, thus aiding in the determination or the validity/invalidity of the theory.

A scientific law is a concise verbal or mathematical statement of a relation that expresses a fundamental principle of a theory, like Newton's law of universal gravitation.


Theory and experiment
Theorists seek to develop mathematical models that both agree with existing experiments and successfully predict future results, while experimentalists devise and perform experiments to test theoretical predictions and explore new phenomena. Although theory and experiment are developed separately, they are strongly dependent upon each other. Progress in physics frequently comes about when experimentalists make a discovery that existing theories cannot explain, or when new theories generate experimentally testable predictions, which inspire new experiments.
Physicists who work at the interplay of theory and experiment are called phenomenologists. Phenomenologists look at the complex phenomena observed in experiment and work to relate them to fundamental theory.
Theoretical physics has historically taken inspiration from philosophy; electromagnetism was unified this way. Beyond the known universe, the field of theoretical physics also deals with hypothetical issues, such as parallel universes, a multiverse, and higher dimensions. Theorists invoke these ideas in hopes of solving particular problems with existing theories. They then explore the consequences of these ideas and work toward making testable predictions.

Experimental physics informs, and is informed by, engineering and technology. Experimental physicists involved in basic research design and perform experiments with equipment such as particle accelerators and lasers, whereas those involved in applied research often work in industry, developing technologies such as magnetic resonance imaging (MRI) and transistors. Feynman has noted that experimentalists may seek areas which are not well-explored by theorists.




Scope and aims
Physics covers a wide range of phenomena, from elementary particles (such as quarks, neutrinos and electrons) to the largest superclusters of galaxies. Included in these phenomena are the most basic objects composing all other things. Therefore physics is sometimes called the "fundamental science". Physics aims to describe the various phenomena that occur in nature in terms of simpler phenomena. Thus, physics aims to both connect the things observable to humans to root causes, and then connect these causes together.
For example, the ancient Chinese observed that certain rocks (lodestone) were attracted to one another by some invisible force. This effect was later called magnetism, and was first rigorously studied in the 17th century. A little earlier than the Chinese, the ancient Greeks knew of other objects such as amber, that when rubbed with fur would cause a similar invisible attraction between the two. This was also first studied rigorously in the 17th century, and came to be called electricity. Thus, physics had come to understand two observations of nature in terms of some root cause (electricity and magnetism). However, further work in the 19th century revealed that these two forces were just two different aspects of one force—electromagnetism. This process of "unifying" forces continues today, and electromagnetism and the weak nuclear force are now considered to be two aspects of the electroweak interaction. Physics hopes to find an ultimate reason (Theory of Everything) for why nature is as it is (see section Current research below for more information).


Research fields
Contemporary research in physics can be broadly divided into condensed matter physics; atomic, molecular, and optical physics; particle physics; astrophysics; geophysics and biophysics. Some physics departments also support research in Physics education.
Since the 20th century, the individual fields of physics have become increasingly specialized, and today most physicists work in a single field for their entire careers. "Universalists" such as Albert Einstein (1879–1955) and Lev Landau (1908–1968), who worked in multiple fields of physics, are now very rare.



Condensed matter
Condensed matter physics is the field of physics that deals with the macroscopic physical properties of matter. In particular, it is concerned with the "condensed" phases that appear whenever the number of constituents in a system is extremely large and the interactions between the constituents are strong.
The most familiar examples of condensed phases are solids and liquids, which arise from the bonding and electromagnetic force between atoms. More exotic condensed phases include the superfluid and the Bose–Einstein condensate found in certain atomic systems at very low temperature, the superconducting phase exhibited by conduction electrons in certain materials, and the ferromagnetic and antiferromagnetic phases of spins on atomic lattices.
Condensed matter physics is by far the largest field of contemporary physics. Historically, condensed matter physics grew out of solid-state physics, which is now considered one of its main subfields. The term condensed matter physics was apparently coined by Philip Anderson when he renamed his research group—previously solid-state theory—in 1967.
In 1978, the Division of Solid State Physics at the American Physical Society was renamed as the Division of Condensed Matter Physics. Condensed matter physics has a large overlap with chemistry, materials science, nanotechnology and engineering.



Atomic, molecular, and optical physics
Atomic, molecular, and optical physics (AMO) is the study of matter–matter and light–matter interactions on the scale of single atoms and molecules. The three areas are grouped together because of their interrelationships, the similarity of methods used, and the commonality of the energy scales that are relevant. All three areas include both classical, semi-classical and quantum treatments; they can treat their subject from a microscopic view (in contrast to a macroscopic view).
Atomic physics studies the electron shells of atoms. Current research focuses on activities in quantum control, cooling and trapping of atoms and ions,[citation needed] low-temperature collision dynamics and the effects of electron correlation on structure and dynamics. Atomic physics is influenced by the nucleus (see, e.g., hyperfine splitting), but intra-nuclear phenomena such as fission and fusion are considered part of high-energy physics.
Molecular physics focuses on multi-atomic structures and their internal and external interactions with matter and light. Optical physics is distinct from optics in that it tends to focus not on the control of classical light fields by macroscopic objects, but on the fundamental properties of optical fields and their interactions with matter in the microscopic realm.


High-energy physics (particle physics)
Particle physics is the study of the elementary constituents of matter and energy, and the interactions between them. It may also be called "high-energy physics", because many elementary particles do not occur naturally, but are created only during high-energy collisions of other particles, as can be detected in particle accelerators.

Currently, the interactions of elementary particles are described by the Standard Model. The model accounts for the 12 known particles of matter (quarks and leptons) that interact via the strong, weak, and electromagnetic fundamental forces. Dynamics are described in terms of matter particles exchanging gauge bosons (gluons, W and Z bosons, and photons, respectively). The Standard Model also predicts a particle known as the Higgs boson, the existence of which has not yet been verified; as of 2010, searches for it are underway in the Tevatron at Fermilab and in the Large Hadron Collider at CERN.


Astrophysics
Astrophysics and astronomy are the application of the theories and methods of physics to the study of stellar structure, stellar evolution, the origin of the solar system, and related problems of cosmology. Because astrophysics is a broad subject, astrophysicists typically apply many disciplines of physics, including mechanics, electromagnetism, statistical mechanics, thermodynamics, quantum mechanics, relativity, nuclear and particle physics, and atomic and molecular physics.
The discovery by Karl Jansky in 1931 that radio signals were emitted by celestial bodies initiated the science of radio astronomy. Most recently, the frontiers of astronomy have been expanded by space exploration. Perturbations and interference from the earth's atmosphere make space-based observations necessary for infrared, ultraviolet, gamma-ray, and X-ray astronomy.
Physical cosmology is the study of the formation and evolution of the universe on its largest scales. Albert Einstein's theory of relativity plays a central role in all modern cosmological theories. In the early 20th century, Hubble's discovery that the universe was expanding, as shown by the Hubble diagram, prompted rival explanations known as the steady state universe and the Big Bang.
The Big Bang was confirmed by the success of Big Bang nucleosynthesis and the discovery of the cosmic microwave background in 1964. The Big Bang model rests on two theoretical pillars: Albert Einstein's general relativity and the cosmological principle. Cosmologists have recently established the ΛCDM model of the evolution of the universe, which includes cosmic inflation, dark energy and dark matter.
Numerous possibilities and discoveries are anticipated to emerge from new data from the Fermi Gamma-ray Space Telescope over the upcoming decade and vastly revise or clarify existing models of the universe. In particular, the potential for a tremendous discovery surrounding dark matter is possible over the next several years. Fermi will search for evidence that dark matter is composed of weakly interacting massive particles, complementing similar experiments with the Large Hadron Collider and other underground detectors.
IBEX is already yielding new astrophysical discoveries: "No one knows what is creating the ENA (energetic neutral atoms) ribbon" along the termination shock of the solar wind, "but everyone agrees that it means the textbook picture of the heliosphere — in which the solar system's enveloping pocket filled with the solar wind's charged particles is plowing through the onrushing 'galactic wind' of the interstellar medium in the shape of a comet — is wrong.